Polymer Technology College, Pod gradom 4 Slovenj Gradec, Slovenia.
Macromol Rapid Commun. 2012 Oct 26;33(20):1731-46. doi: 10.1002/marc.201200393. Epub 2012 Aug 21.
Recently, a series of new monomers and polymerization mechanisms has been applied to the templating of high internal phase emulsions (HIPEs) providing a route to hierarchically porous materials with a range of functionalities and applications. The high degree of control over the pore size is another attractive feature of these materials. Usually, the continuous phase contains monomers, the droplet phase is used to template the large, primary pores, which are interconnected by secondary pores. The addition of nonpolymerizable components to the continuous phase can result in phase separation during polymerization and tertiary pores. Applications include polymer supports for catalysis and synthesis, separation and filtration, cell culture media, enzyme supports, and structural and isolation applications.
最近，一系列新的单体和聚合机制已被应用于高内相乳液（HIPE）的模板化，为具有各种功能和应用的分级多孔材料提供了一种途径。这些材料的另一个吸引人的特点是对孔径的高度控制。通常，连续相包含单体，液滴相用于模板化大的初级孔，这些初级孔通过次级孔相互连接。向连续相中添加不可聚合的成分会导致聚合过程中的相分离和三级孔。应用包括用于催化和合成、分离和过滤、细胞培养基、酶载体以及结构和隔离应用的聚合物载体。
