[{Fe(CO)3}4{SnI}6I4]2-：首个双金属金刚烷样簇合物。
[{Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.
机构信息
Institut für Anorganische Chemie, Karlsruhe Institute of Technology, Germany.
出版信息
Chemistry. 2012 Oct 22;18(43):13600-4. doi: 10.1002/chem.201202683. Epub 2012 Sep 17.
PMID:22987543
Abstract
Show some metal: the first bimetallic adamantane-like cluster, {Fe(CO)(3)}(4){SnI}(6)I(4), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations.
摘要
展示一些金属
首例双金属金刚烷样簇 {Fe(CO)(3)}(4){SnI}(6)I(4) 通过离子液体基合成制备而成。根据键长考虑、FT-IR 和 (119)Sn Mössbauer 光谱以及 DFT 计算，验证了铁和锡的价态。
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