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展示热力学相变和玻璃化转变的简单可解能量景观模型。

Simple solvable energy-landscape model that shows a thermodynamic phase transition and a glass transition.

作者信息

Naumis Gerardo G

机构信息

Instituto de Física, Universidad Nacional Autónoma de México (UNAM), Apartado Postal 20-364, 01000 México, Distrito Federal, Mexico.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jun;85(6 Pt 1):061505. doi: 10.1103/PhysRevE.85.061505. Epub 2012 Jun 28.

Abstract

When a liquid melt is cooled, a glass or phase transition can be obtained depending on the cooling rate. Yet, this behavior has not been clearly captured in energy-landscape models. Here, a model is provided in which two key ingredients are considered in the landscape, metastable states and their multiplicity. Metastable states are considered as in two level system models. However, their multiplicity and topology allows a phase transition in the thermodynamic limit for slow cooling, while a transition to the glass is obtained for fast cooling. By solving the corresponding master equation, the minimal speed of cooling required to produce the glass is obtained as a function of the distribution of metastable states.

摘要

当液态熔体冷却时,根据冷却速率可得到玻璃态或相变。然而,这种行为在能量景观模型中尚未得到清晰的描述。在此,提供了一个模型,其中在景观中考虑了两个关键要素,即亚稳态及其多重性。亚稳态的考虑方式与两能级系统模型相同。然而,它们的多重性和拓扑结构使得在缓慢冷却的热力学极限下会发生相变,而在快速冷却时则会转变为玻璃态。通过求解相应的主方程,得出了产生玻璃态所需的最小冷却速度,它是亚稳态分布的函数。

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