Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, Zaragoza, Spain.
Phys Rev Lett. 2012 Sep 7;109(10):107202. doi: 10.1103/PhysRevLett.109.107202. Epub 2012 Sep 4.
We have studied the incommensurate-ordered phase in overdoped La0.4Sr1.6MnO4 by resonant x-ray diffraction at the Mn K edge. Weak resonant superlattice (h±0.2 h±0.2 0) and (h±0.4 h±0.4 0) reflections of the tetragonal structure were found below ~240 K. The energy, azimuth angle, and polarization dependencies of the resonant scattering have revealed sinusoidal modulations of the oxygen motions that are transverse and longitudinal to the tetragonal [110] direction. This result discards (Mn(3+),Mn(4+))-like stripe-type order but point to a charge-density-modulation picture.
我们通过在 Mn K 边缘的共振 x 射线衍射研究了过掺杂 La0.4Sr1.6MnO4 中的非共格有序相。在~240 K 以下发现了四方结构的弱共振超晶格(h±0.2 h±0.2 0)和(h±0.4 h±0.4 0)反射。共振散射的能量、方位角和偏振依赖性揭示了氧运动的正弦调制,这些运动是横向和纵向于四方[110]方向的。这一结果排除了(Mn(3+),Mn(4+))类似的条纹型有序,但指向了电荷密度调制的图景。