Patel Rajesh
Department of Physics, Sardar Vallabhbhai Patel Campus, Bhavnagar University, Bhavnagar 364002, Gujarat, India.
Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Jul;86(1 Pt 2):016324. doi: 10.1103/PhysRevE.86.016324. Epub 2012 Jul 30.
A significant effect of aggregation dynamics for aqueous ferrofluid (AF) and kerosene based ferrofluid (KF) using magnetic field dependent capillary viscosity and magneto-optical relaxation measurements is studied. For better comparison parameters of AF and KF are kept similar. Ferrohydrodynamic equations of chain forming ferrofluids, dilute ferrofluids, and Brownian dynamic simulations are compared. It is observed that the rotational viscosity of AF is larger than that of KF due to field induced aggregates in it and strong dipolar interactions. It is also observed that at Ωτ ~ 0.04 both AF and KF viscosity becomes almost similar, suggesting similar behavior at that shear rate. The magneto-optical relaxation in AF exhibits nonexponential behavior when relaxed from higher magnetic field and follows irreversible thermodynamics, whereas for KF the relaxation is exponential and follows the effective field method. This discrepancy is explained based on aggregation dynamics of magnetic particles. Results are well described by the corresponding theoretical models.
利用磁场依赖的毛细管粘度和磁光弛豫测量方法,研究了水性铁磁流体(AF)和煤油基铁磁流体(KF)的聚集动力学的显著影响。为了进行更好的比较,AF和KF的参数保持相似。比较了链状形成铁磁流体、稀铁磁流体的铁流体动力学方程以及布朗动力学模拟。观察到,由于其中的场诱导聚集体和强偶极相互作用,AF的旋转粘度大于KF的旋转粘度。还观察到,在Ωτ~0.04时,AF和KF的粘度几乎变得相似,表明在该剪切速率下具有相似的行为。当从较高磁场弛豫时,AF中的磁光弛豫表现出非指数行为,并遵循不可逆热力学,而对于KF,弛豫是指数性的,并遵循有效场方法。基于磁性颗粒的聚集动力学对这种差异进行了解释。相应的理论模型很好地描述了结果。