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化学功能化石墨烯的增强筛选。

Enhanced screening in chemically functionalized graphene.

机构信息

Radboud University of Nijmegen, Institute for Molecules and Materials, Nijmegen, The Netherlands.

出版信息

Phys Rev Lett. 2012 Oct 12;109(15):156601. doi: 10.1103/PhysRevLett.109.156601. Epub 2012 Oct 9.

Abstract

Resonant scatterers such as hydrogen adatoms can strongly enhance the low-energy density of states in graphene. Here, we study the impact of these impurities on electronic screening. We find a two-faced behavior: Kubo formula calculations reveal an increased dielectric function ε upon creation of midgap states but no metallic divergence of the static ε at small momentum transfer q→0. This bad metal behavior manifests also in the dynamic polarization function and can be directly measured by means of electron energy loss spectroscopy. A new length scale l(c) beyond which screening is suppressed emerges, which we identify with the Anderson localization length.

摘要

共振散射体,如氢原子,可强烈增强石墨烯中的低能态密度。在此,我们研究了这些杂质对电子屏蔽的影响。我们发现了一种两面性的行为:Kubo 公式计算表明,在形成带隙态时介电函数 ε 增加,但在小动量转移 q→0 时,静态 ε 没有金属发散。这种不良金属行为也表现在动态极化函数中,可以通过电子能量损失谱直接测量。出现了一个新的长度尺度 l(c),在此尺度之外屏蔽被抑制,我们将其识别为安德森局域化长度。

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