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四（μ-2-苯基喹啉-4-羧酸根-κ(2)O:O'）双[（甲醇-κO）铜（II）]

Tetra-kis(μ-2-phenyl-quinoline-4-carboxyl-ato-κ(2)O:O')bis-[(methanol-κO)copper(II)].

作者信息

Guo Junfang, Yan Guoping

机构信息

School of Materials Science and Engineering, Wuhan Institute of Technology, 430073 Wuhan People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1296. doi: 10.1107/S1600536812039839. Epub 2012 Sep 26.

DOI:10.1107/S1600536812039839
PMID:23125612
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3470168/
Abstract

The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol-ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl-ate groups from different ligands at the basal plane and an O atom of a methanol mol-ecule at the axial position. In the crystal, the dinuclear complex mol-ecules are linked into one-dimensional supra-molecular columns parallel to the b axis by O-H⋯N hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.7259 (11) Å].

摘要

标题配合物[Cu₂(C₁₆H₁₀NO₂)₄(CH₃OH)₂]由中心对称的轮状双核中性分子组成，其中每个Cu(II)原子在略呈扭曲的四方锥几何构型中，通过来自不同配体的羧酸根基团的四个O原子在基面配位，以及一个甲醇分子的O原子在轴向位置配位。在晶体中，双核配合物分子通过O—H⋯N氢键和π-π堆积相互作用[质心-质心距离 = 3.7259 (11) Å]连接成平行于b轴的一维超分子柱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f024/3470168/8c4062a82162/e-68-m1296-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f024/3470168/929fb0e24a6f/e-68-m1296-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f024/3470168/8c4062a82162/e-68-m1296-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f024/3470168/929fb0e24a6f/e-68-m1296-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f024/3470168/8c4062a82162/e-68-m1296-fig2.jpg

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