Guo Junfang, Yan Guoping
School of Materials Science and Engineering, Wuhan Institute of Technology, 430073 Wuhan People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1296. doi: 10.1107/S1600536812039839. Epub 2012 Sep 26.
The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol-ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl-ate groups from different ligands at the basal plane and an O atom of a methanol mol-ecule at the axial position. In the crystal, the dinuclear complex mol-ecules are linked into one-dimensional supra-molecular columns parallel to the b axis by O-H⋯N hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.7259 (11) Å].
标题配合物[Cu₂(C₁₆H₁₀NO₂)₄(CH₃OH)₂]由中心对称的轮状双核中性分子组成,其中每个Cu(II)原子在略呈扭曲的四方锥几何构型中,通过来自不同配体的羧酸根基团的四个O原子在基面配位,以及一个甲醇分子的O原子在轴向位置配位。在晶体中,双核配合物分子通过O—H⋯N氢键和π-π堆积相互作用[质心-质心距离 = 3.7259 (11) Å]连接成平行于b轴的一维超分子柱。