在桨轮型 Ru 二聚体链化合物中的 CO2 超吸收：取决于链间相互作用的门控开启性能。
CO2 superabsorption in a paddlewheel-type Ru dimer chain compound: gate-open performance dependent on inter-chain interactions.
机构信息
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
出版信息
Chem Commun (Camb). 2013 Feb 25;49(16):1594-6. doi: 10.1039/c2cc36153a.
PMID:23174816
Abstract
A porous one-dimensional coordination chain compound, [Ru(2)(p-F-PhCO(2))(4)(phz)] (; p-F-PhCO(2)(-) = para-fluorobenzoate; phz = phenazine) derived by drying its nitrobenzene-solvated compound, specifically adsorbs CO(2) at 195 K in a stepwise sorption manner.
摘要
一种多孔一维配位链化合物，[Ru(2)(p-F-PhCO(2))(4)(phz)]（; p-F-PhCO(2)(-) = 对氟苯甲酸盐；phz = 吩嗪）由其硝基苯溶剂化物干燥得到，在 195 K 下以分步吸附的方式特异性吸附 CO(2)。
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