Ahmady-Asbchin Salman
Department of Applied biology, Faculty of science, University of Ilam, Islamic Republic of Iran
Toxicol Ind Health. 2015 Jan;31(1):52-9. doi: 10.1177/0748233712468016. Epub 2012 Dec 6.
Biosorption of copper (Cu) ions from aqueous solutions has been studied in a batch system using a Bacillus species AEJ-89 isolated from Maranjab desert soil. The optimum conditions of biosorption were determined by investigating the initial pH, contact time, and the initial concentrations of metal ions at constant temperature (25°C). The maximum biosorption of Cu ions was observed at pH 5.0 ± 0.1. Biosorption equilibrium times for Cu (II) ions were observed in 30 min. The maximum biosorption capacities of Cu (II) ions on Bacillus species AEJ-89 were determined to be 0.48 mmol g(-1) at 200 mg l(-1) concentration. The experimental adsorption data were fitted to Langmuir isotherm model. The interactions between metal ions and functional groups on the cell wall surface of the biomass were confirmed by Fourier transform infrared spectroscopy analysis. Cu (II) ions were removed from metal-laden biomass after desorption treatments by the addition of different desorbing solutions. The results indicated that the bacterial isolate Bacillus species AEJ-89 is a suitable biosorbent for the removal of Cu (II) ions from aqueous solutions.
在间歇系统中,利用从马兰贾布沙漠土壤中分离出的芽孢杆菌属AEJ - 89菌株,研究了从水溶液中生物吸附铜(Cu)离子的情况。通过在恒温(25°C)下研究初始pH值、接触时间和金属离子初始浓度,确定了生物吸附的最佳条件。在pH 5.0 ± 0.1时观察到铜离子的最大生物吸附量。铜(II)离子的生物吸附平衡时间为30分钟。在浓度为200 mg l(-1)时,芽孢杆菌属AEJ - 89对铜(II)离子的最大生物吸附容量测定为0.48 mmol g(-1)。实验吸附数据符合朗缪尔等温线模型。通过傅里叶变换红外光谱分析证实了金属离子与生物质细胞壁表面官能团之间的相互作用。通过添加不同的解吸溶液进行解吸处理后,从负载金属的生物质中去除了铜(II)离子。结果表明,细菌分离株芽孢杆菌属AEJ - 89是从水溶液中去除铜(II)离子的合适生物吸附剂。