Instituto de Física, Universidade de São Paulo, P.O. Box 66318, São Paulo 05314-970, Brazil.
J Phys Chem B. 2013 Mar 14;117(10):2985-91. doi: 10.1021/jp312284a. Epub 2013 Mar 6.
We present a generalization of the Poisson-Nernst-Planck model for a dielectric liquid containing two groups of ions limited by Ohmic electrodes. The theoretical results are used to interpret experimental results of impedance spectroscopy of pure water limited by electrodes of different metallic materials. The agreement between theoretical predictions of the presented model and experimental data obtained with pure water is rather good for all types of electrodes.
我们提出了一个泊松-纳斯特-普朗克模型的推广,用于描述含有两组离子的介电液体,这些离子受到欧姆电极的限制。理论结果用于解释不同金属材料电极限制的纯水阻抗谱实验结果。对于所有类型的电极,所提出模型的理论预测与纯水实验数据之间的一致性相当好。