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甲醛:催化氧化作为一种有前途的温和消除方法。

Formaldehyde: catalytic oxidation as a promising soft way of elimination.

机构信息

Université de Lille1, Unité de Catalyse et Chimie du Solide, UMR CNRS 8181, 59652 Villeneuve d'Ascq, France.

出版信息

ChemSusChem. 2013 Apr;6(4):578-92. doi: 10.1002/cssc.201200809. Epub 2013 Mar 1.

Abstract

Compared to other molecules such as benzene, toluene, xylene, and chlorinated compounds, the catalytic oxidation of formaldehyde has been studied rarely. However, standards for the emission level of this pollutant will become more restrictive because of its extreme toxicity even at very low concentrations in air. As a consequence, the development of a highly efficient process for its selective elimination is needed. Complete catalytic oxidation of formaldehyde into CO2 and H2 O using noble-metal-based catalysts is a promising method to convert this pollutant at room temperature, making this process energetically attractive from an industrial point of view. However, the development of a less expensive active phase is required for a large-scale industrial development. Nanomaterials based on oxides of manganese are described as the most promising catalysts. The objective of this Minireview is to present promising recent studies on the removal of formaldehyde through heterogeneous catalysis to stimulate future research in this topic.

摘要

与苯、甲苯、二甲苯和氯化物等其他分子相比,甲醛的催化氧化研究较少。然而,由于其在空气中即使浓度非常低也具有极高的毒性,因此这种污染物的排放标准将变得更加严格。因此,需要开发一种高效的选择性消除方法。使用贵金属基催化剂将甲醛完全催化氧化为 CO2 和 H2 O 是在室温下转化这种污染物的一种很有前途的方法,从工业角度来看,该过程在能量上具有吸引力。然而,需要开发一种更廉价的活性相以实现大规模的工业发展。基于锰氧化物的纳米材料被描述为最有前途的催化剂。这篇综述的目的是介绍通过多相催化去除甲醛的有前途的最新研究,以激发该主题的未来研究。

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