Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Chem Commun (Camb). 2013 Apr 18;49(30):3122-4. doi: 10.1039/c3cc40931g. Epub 2013 Mar 8.
Evaporative self-assembly of dilute solutions containing single-chain polymeric nanoparticles results in characteristic morphologies imaged using atomic force microscopy. Quantitative comparison of experimental data to morphologies obtained by lattice-gas simulations shows that the nonequilibrium patterns emerge from a complex interplay between dewetting, solvent evaporation and nanoparticle diffusion.
含有单链聚合物纳米粒子的稀溶液的蒸发自组装导致使用原子力显微镜成像的特征形态。将实验数据与晶格气体模拟得到的形态进行定量比较表明,非平衡图案是由去湿、溶剂蒸发和纳米粒子扩散之间的复杂相互作用产生的。