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1-{(Z)-[3-(1-羟乙基)苯胺基]亚甲基}萘-2(1H)-酮

1-{(Z)-[3-(1-Hy-droxy-eth-yl)anilino]methyl-idene}naphthalen-2(1H)-one.

作者信息

Horton Peter N, Akkurt Mehmet, Mohamed Shaaban K, Abdelhamid Antar A, Marzouk Adel A

机构信息

School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ England, England.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o106. doi: 10.1107/S1600536812050635. Epub 2012 Dec 19.

Abstract

In the title compound, C19H17NO2, the dihedral angle between the benzene ring and the naphthalene ring system is 9.72 (5)°, while the torsion angle of the C-N-C-C bridging group is 179.24 (17)°. The methyl group of the 1-phenyl-ethanol moiety is disordered over two positions with a refined occupancy ratio of 0.775 (5):0.225 (5). The mol-ecular conformation is stabil-ized by an intra-molecular N-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming zigzag chains propagating along the c-axis direction. Neighbouring chains are linked via C-H⋯O inter-actions, forming a two-dimensional slab-like network parallel to the bc plane.

摘要

在标题化合物C₁₉H₁₇NO₂中,苯环与萘环体系之间的二面角为9.72 (5)°,而C-N-C-C桥连基团的扭转角为179.24 (17)°。1-苯基乙醇部分的甲基在两个位置上无序,精修占有率比为0.775 (5):0.225 (5)。分子构象通过分子内N-H⋯O氢键得以稳定,该氢键形成一个S(6)环模式。在晶体中,分子通过O-H⋯O氢键相连,形成沿c轴方向传播的锯齿链。相邻的链通过C-H⋯O相互作用相连,形成平行于bc平面的二维板状网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed45/3588315/bef708615a47/e-69-0o106-fig1.jpg

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