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[活性氧化铝除磷及回收的研究]

[Study on phosphate removal and recovery by activated alumina].

作者信息

Meng Wen-Na, Xie Jie, Wu De-Yi, Zhang Zhen-Jia, Kong Hai-Nan

机构信息

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.

出版信息

Huan Jing Ke Xue. 2013 Jan;34(1):231-6.

Abstract

Activated alumina was studied for removing phosphate from water, and the recovery of adsorbed phosphate on activated aluminum oxide was also tested. Phosphate solution was prepared using distilled water, tap water and Luoshijiang River water, respectively. All the phosphate adsorption tests using activated alumina were proved to be well fitted with Langmuir isotherm and the respective maximum adsorption amount were 20.88, 32.15 and 29.85 mg x g(-1), respectively. The presence of electrolyte in water could be a positive factor for phosphate removal. As the pH value of phosphate solution became lower the Zeta potential of activated alumina increased, which could enhance the phosphate removal efficiency of activated alumina. The recovery tests indicated that NaOH (0.1 mol x L(-1)) solution could almost completely extract the phosphate adsorbed by activated alumina.

摘要

研究了活性氧化铝用于去除水中磷酸盐的性能,并测试了活性氧化铝对吸附磷酸盐的回收情况。分别用蒸馏水、自来水和洛石河河水配制磷酸盐溶液。所有使用活性氧化铝的磷酸盐吸附试验均证明符合朗缪尔等温线,其各自的最大吸附量分别为20.88、32.15和29.85 mg·g⁻¹。水中电解质的存在可能是去除磷酸盐的一个积极因素。随着磷酸盐溶液pH值降低,活性氧化铝的ζ电位升高,这可提高活性氧化铝对磷酸盐的去除效率。回收试验表明,0.1 mol·L⁻¹的NaOH溶液几乎可以完全提取被活性氧化铝吸附的磷酸盐。

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