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1-羟基亚乙基-1,1-二膦酸在工业锅炉锅炉水中的应用。

Application of 1-hydroxyethylidene-1, 1-diphosphonic acid in boiler water for industrial boilers.

机构信息

Changsha University of Science & Technology, Changsha, Chinese Hunan, China.

出版信息

Water Sci Technol. 2013;67(7):1544-50. doi: 10.2166/wst.2013.021.

Abstract

The primary method used for boiler water treatment is the addition of chemicals to industrial boilers to prevent corrosion and scaling. The static scale inhibition method was used to evaluate the scale inhibition performance of 1-hydroxyethylidene-1, 1-diphosphonic acid (HEDP). Autoclave static experiments were used to study the corrosion inhibition properties of the main material for industrial boilers (20# carbon steel) with an HEDP additive in the industrial boiler water medium. The electrochemical behavior of HEDP on carbon steel corrosion control was investigated using electrochemical impedance spectroscopy and Tafel polarization techniques. Experimental results indicate that HEDP can have a good scale inhibition effect when added at a quantity of 5 to 7 mg/L at a test temperature of not more than 100 °C. To achieve a high scale inhibition rate, the HEDP dosage must be increased when the test temperature exceeds 100 °C. Electrochemical and autoclave static experimental results suggest that HEDP has a good corrosion inhibition effect on 20# carbon steel at a concentration of 25 mg/L. HEDP is an excellent water treatment agent.

摘要

锅炉水的处理主要采用向工业锅炉中添加化学物质的方法,以防止腐蚀和结垢。本文采用静态阻垢法评价了 1-羟基亚乙基-1,1-二膦酸(HEDP)的阻垢性能。采用高压釜静态实验,研究了含 HEDP 添加剂的工业锅炉用水介质中工业锅炉主要材料(20#碳钢)的缓蚀性能。利用电化学阻抗谱和塔菲尔极化技术研究了 HEDP 对碳钢腐蚀控制的电化学行为。实验结果表明,在测试温度不超过 100°C 时,添加 5 至 7mg/L 的 HEDP 可达到良好的阻垢效果。当测试温度超过 100°C 时,必须增加 HEDP 的用量以获得高的阻垢率。电化学和高压釜静态实验结果表明,HEDP 在浓度为 25mg/L 时对 20#碳钢具有良好的缓蚀效果。HEDP 是一种优良的水处理剂。

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