Department of Physics, Tianjin University, Tianjin 300072, PR China.
Spectrochim Acta A Mol Biomol Spectrosc. 2013 Jul;111:188-91. doi: 10.1016/j.saa.2013.04.003. Epub 2013 Apr 10.
Natural fibrous gypsum is colored electrolytically at near room temperatures and under various voltages using a pointed anode and a flat cathode. The SO4(-), SO3(-), SO2(-) and O(-) lattice defects are produced in the colored natural fibrous gypsum. No visible characteristic absorption band in the ultraviolet and visible wavelength regions is observed in the optical absorption spectrum of the natural fibrous gypsum before the electrolytic coloration. The characteristic absorption bands of the SO4(-), SO3(-), SO2(-) and O(-) lattice defects are observed in the optical absorption spectra of the colored natural fibrous gypsum. The production of the lattice defects is explained. Current-time curve for the electrolytic coloration of the natural fibrous gypsum and its relationship with the electrolytic coloration processes are given.
天然纤维石膏在室温附近和不同电压下使用尖形阳极和平板阴极进行电解着色。有色天然纤维石膏中产生了 SO4(-)、SO3(-)、SO2(-) 和 O(-) 晶格缺陷。在电解着色之前,天然纤维石膏的紫外可见波长区域的光吸收光谱中没有观察到可见的特征吸收带。有色天然纤维石膏的光吸收光谱中观察到了 SO4(-)、SO3(-)、SO2(-) 和 O(-) 晶格缺陷的特征吸收带。解释了晶格缺陷的产生。给出了天然纤维石膏电解着色的电流-时间曲线及其与电解着色过程的关系。