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纤维素晶须含量对聚乙烯-醋酸乙烯共聚物/纤维素复合材料性能的影响。

Effect of cellulose whisker content on the properties of poly(ethylene-co-vinyl acetate)/cellulose composites.

机构信息

Department of Chemistry, National Institute of Technology, Calicut 673601, India.

出版信息

Carbohydr Polym. 2013 Jun 20;95(2):773-9. doi: 10.1016/j.carbpol.2013.02.039. Epub 2013 Mar 4.

Abstract

The reinforcing effect of cellulose whiskers, produced from banana waste fibres, has been investigated using poly(ethylene-co-vinyl acetate) [EVA]/cellulose whisker composites. Cellulose whiskers, approximately 300 nm long and 30 nm wide, were obtained via a sulphuric acid hydrolysis method. The effects of the cellulose whisker loading on the thermal properties, mechanical properties and on the morphological features of the composites have been investigated. EVA copolymer with a vinyl acetate segment content of 40% has been used for composite fabrication. The developed composites showed superior thermal and mechanical properties relative to that of the EVA copolymer alone. Three theoretical models, namely the Halpin-Tsai model, the Kerner model and the Nicolais-Narkis model have been employed to provide a basis for the comparison of the results with the observations from the tensile investigations.

摘要

利用香蕉废料纤维制备的纤维素晶须增强了聚乙烯-醋酸乙烯共聚物[EVA]/纤维素晶须复合材料的性能。纤维素晶须通过硫酸水解法制备,长度约为 300nm,宽度约为 30nm。研究了纤维素晶须负载量对复合材料的热性能、力学性能和形态特征的影响。采用乙烯-醋酸乙烯共聚物(醋酸乙烯含量为 40%)进行复合材料的制备。与纯 EVA 共聚物相比,所开发的复合材料具有更优异的热性能和力学性能。采用了三种理论模型,即 Halpin-Tsai 模型、Kerner 模型和 Nicolais-Narkis 模型,为将结果与拉伸研究中的观察结果进行比较提供了依据。

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