二氧介导的{Fe(NO)2}9 双亚硝酰铁配合物转化为鲁辛氏红酯。
Dioxygen mediated conversion of {Fe(NO)2}9 dinitrosyl iron complexes to Roussin's red esters.
机构信息
Department of Chemistry, Brown University, Providence, RI 02912, USA.
出版信息
Chem Commun (Camb). 2013 Jun 21;49(49):5550-2. doi: 10.1039/c3cc40352a.
PMID:23675584
Abstract
The reactivity of a series of {Fe(NO)2}(9) dinitrosyl iron complexes bearing thiolate ligands with molecular oxygen is reported. These reactions result in the formation of the corresponding Roussin's red esters along with thiolate oxidation. This reactivity is contrasted with that previously reported for {Fe(NO)2}(10) complexes.
摘要
报道了一系列带有硫醇配体的{Fe(NO)2}(9)二硝基金属配合物与分子氧的反应活性。这些反应导致相应的 Roussin 红酯的形成以及硫醇的氧化。这种反应活性与之前报道的{Fe(NO)2}(10)配合物的反应活性形成对比。
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