Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, 400076, India.
J Org Chem. 2013 Jun 21;78(12):5949-54. doi: 10.1021/jo400598p. Epub 2013 Jun 4.
Ferric nitrate with catalytic TEMPO has been identified as a useful reagent for regio- and stereoselective nitration of a wide variety of aromatic, aliphatic, and heteroaromatic olefins. This reaction provided nitroolefins in preparatively useful yields with excellent E-selectivity. Due to its mild nature and operational simplicity, the present protocol is expected to find application in synthetic setup.
三价铁硝酸盐与催化 TEMPO 已被确定为一种有用的试剂，可用于区域和立体选择性硝化各种芳香族、脂肪族和杂环烯烃。该反应以优异的 E-选择性提供了具有制备有用收率的硝基烯烃。由于其温和的性质和操作简单，本方案有望在合成中得到应用。
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