Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, New Jersey 08544, USA.
Langmuir. 2013 Jun 25;29(25):7857-63. doi: 10.1021/la4011532. Epub 2013 Jun 5.
We investigate experimentally the evaporation of liquid accumulated on a pair of parallel fibers, rigid or flexible. The liquid wetting the fibers can adopt two distinct morphologies: a compact drop shape, whose evaporation dynamics is similar to that of an isolated aerosol droplet, or a long liquid column of constant cross-section, whose evaporation dynamics depends upon the aspect ratio of the column. We thus find that the evaporation rate is constant for drops, while it increases strongly for columns as the interfiber distance decreases, and we propose a model to explain this behavior. When the fibers are flexible, the transition from drops to columns can be induced by the deformation of the fibers because of the capillary forces applied by the drop. Thus, we find that the evaporation rate increases with increasing flexibility. Furthermore, complex morphology transitions occur upon drying, which results in spreading of the drop as it evaporates.
我们实验研究了在一对平行纤维(刚性或柔性)上积累的液体的蒸发。浸润纤维的液体可以呈现两种截然不同的形态:紧密的液滴形状,其蒸发动力学类似于孤立气溶胶液滴;或具有恒定横截面的长液柱,其蒸发动力学取决于柱的纵横比。因此,我们发现液滴的蒸发速率是恒定的,而随着纤维间距离的减小,液柱的蒸发速率会强烈增加,我们提出了一个模型来解释这种行为。当纤维是柔性时,由于液滴施加的毛细力,纤维的变形可以诱导从液滴到液柱的转变。因此,我们发现蒸发速率随着纤维的柔韧性的增加而增加。此外,在干燥过程中会发生复杂的形态转变,导致液滴在蒸发过程中扩散。