多融合卟啉——扩展π共轭对光学和电化学性质的影响。
Multiply-fused porphyrins--effects of extended π-conjugation on the optical and electrochemical properties.
机构信息
Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Japan.
出版信息
Chem Commun (Camb). 2013 Jul 7;49(53):5939-41. doi: 10.1039/c3cc42831a.
PMID:23715087
Abstract
A novel quadruply-fused porphyrin has been synthesized with a facilely prepared precursor in a high yield. A detailed comparison of the physical properties of a series of fused porphyrins revealed remarkable effects of the ring fusion on lowering LUMO levels rather than HOMO levels.
摘要
一种新型的四重融合卟啉已通过一种易于制备的前体制备高收率地合成。一系列融合卟啉的物理性质的详细比较表明，环融合对降低 LUMO 能级而不是 HOMO 能级有显著的影响。
Zotero 插件