结构异构导致基于间苯二甲酸的铟（III）框架中质子电导率的变化。
Structural isomerism leading to variable proton conductivity in indium(III) isophthalic acid based frameworks.
机构信息
Physical/Materials Chemistry Division, CSIR National Chemical Laboratory, Dr Homi Bhabha Road, Pune 411008, India.
出版信息
Chem Commun (Camb). 2013 Jul 14;49(55):6197-9. doi: 10.1039/c3cc41939h.
PMID:23732259
Abstract
Proton conductivity has been studied thoroughly in two isomeric In(III)-isophthalate based MOFs. In-IA-2D-1 is capable of showing proton conductivity (3.4 × 10(-3) S cm(-1)) under humidified conditions (98% RH), whereas In-IA-2D-2 can conduct protons (2.6 × 10(-5) S cm(-1)) under humidified as well as anhydrous conditions.
摘要
在两种异构的基于 In(III)-间苯二甲酸的 MOFs 中，质子传导性得到了深入研究。In-IA-2D-1 在加湿条件（98% RH）下具有质子传导性（3.4×10^(-3) S cm^(-1))，而 In-IA-2D-2 在加湿和无水条件下都能传导质子（2.6×10^(-5) S cm^(-1))。
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