CNRS, LCC (Laboratoire de Chimie de Coordination), Toulouse, France.
Langmuir. 2013 Jul 16;29(28):8983-8. doi: 10.1021/la401371c. Epub 2013 Jul 1.
Although molecular metals have been known for decades, their insolubility, low vapor pressure, and synthesis routes have prevented them from being integrated into electronic devices. We have prepared stable colloidal solutions of the organic metal TTF-TCNQ that overcome such difficulties. The solutions contain well-dispersed nanoparticles stabilized by long alkyl chain amines. They afford soluble powders by evaporation and homogeneous thin films by drop-casting. Powders and films show room temperature conductivities in the 0.01-0.1 S cm(-1) range.
虽然分子金属已经存在了几十年,但它们的不溶性、低蒸气压以及合成途径使得它们无法被集成到电子设备中。我们已经制备了稳定的有机金属 TTF-TCNQ 胶体溶液,克服了这些困难。该溶液含有由长链烷基胺稳定的良好分散的纳米粒子。通过蒸发可以得到可溶解的粉末,通过滴铸可以得到均匀的薄膜。粉末和薄膜在室温下的电导率在 0.01-0.1 S cm(-1)范围内。