含胆固醇基共配体的二维配位聚合物的客体响应性。
Guest responsivity of a two-dimensional coordination polymer incorporating a cholesterol-based co-ligand.
机构信息
Department of Chemistry, Faculty of Science, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka, Japan.
出版信息
Dalton Trans. 2013 Dec 7;42(45):15893-7. doi: 10.1039/c3dt51465j. Epub 2013 Jul 23.
PMID:23877189
Abstract
To implement specific guest responsivity, a hydrophobic cholesterol-based co-ligand, cholest-5-en-3-yl-4-isonicotinate (Cholpy), was incorporated into a two-dimensional Hofmann-type Co(II)Ni(II) coordination polymer. The chemically programmed structure successfully demonstrated the unique guest response with remarkable chromatic changes.
摘要
为了实现特定的客体响应性，将一种疏水性的胆固醇基共配体，胆甾-5-烯-3-基-4-异烟酸酯（Cholpy），引入到二维的霍夫曼型 Co(II)Ni(II)配位聚合物中。该化学程序控制的结构成功地展示了具有显著颜色变化的独特客体响应。
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