Department of Materials Science, Fudan University, Shanghai, 200433, China; Institute for Superconducting and Electronic Materials, University of Wollongong, Wollongong, NSW 2522, Australia.
Adv Mater. 2013 Nov 20;25(43):6238-44. doi: 10.1002/adma.201301927. Epub 2013 Aug 21.
3D porous carbon-coated Li3 N nanofibers are successfully fabricated via the electrospinning technique. The as-prepared nanofibers exhibit a highly improved hydrogen-sorption performance in terms of both thermodynamics and kinetics. More interestingly, a stable regeneration can be achieved due to the unique structure of the nanofibers, over 10 cycles of H2 sorption at a temperature as low as 250 °C.
3D 多孔碳包覆 Li3 N 纳米纤维通过静电纺丝技术成功制备。所制备的纳米纤维在热力学和动力学方面表现出了高度改善的吸氢性能。更有趣的是,由于纳米纤维的独特结构,可以实现稳定的再生,在 250°C 的低温下进行了 10 次以上的 H2 吸附循环。