一种全氟多苯基树枝状壳，用于保护光敏卟啉核心。
A perfluorous polyphenyl dendritic shell for the protection of a photosensitizing porphyrazine core.
机构信息
Institute for Chemistry and CINSaT - Center for Interdisciplinary Nanostructure Science and Technology, University of Kassel, Heinrich-Plett-Str. 40, 34132 Kassel, Germany.
出版信息
Chem Commun (Camb). 2013 Oct 21;49(82):9413-5. doi: 10.1039/c3cc45442h.
PMID:24002207
Abstract
The implementation of thirty-two pentafluorophenyl groups in the periphery of a phthalocyanine analogue results in a photosensitizer with a pronounced resistance towards autophotooxidation. The synthesis relies on the microwave-assisted cycloaddition of terminal alkynes to tetrakis(pentafluorophenyl)cyclopentadienone, for which a new route was devised.
摘要
在酞菁类似物的外围实施三十二个五氟苯基基团，可得到一种光敏剂，其对自光氧化具有明显的抗性。该合成依赖于末端炔烃与四（五氟苯基）环戊二烯酮的微波辅助环加成，为此设计了一条新路线。
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