Department of Physics & Astronomy and Guelph-Waterloo Physics Institute, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.
J Chem Phys. 2013 Aug 28;139(8):084702. doi: 10.1063/1.4818989.
We consider the ability of recent measurements on the size of a liquid-like mobile surface region in glasses to provide direct information on the length scale of enhanced surface mobility. While these quantities are strongly related there are important distinctions that limit the ability of measurements to quantify the actual length over which the surface properties change from surface to bulk-like. In particular, we show that for temperatures near the bulk glass transition, measurements of a liquid-like mobile layer may have very limited predictive power when it comes to determining the temperature dependent length scale of enhanced surface mobility near the glass transition temperature. This places important limitations on the ability of measurements of such enhanced surface dynamics to contribute to discussion on the length scale for dynamical correlation in glassy materials.
我们认为,最近对玻璃中类似液体的可移动表面区域大小的测量结果,能够为增强表面流动性的长度尺度提供直接信息。虽然这些量之间存在很强的相关性,但仍存在一些重要的区别,限制了测量结果确定从表面到类似体相的表面性质发生变化的实际长度的能力。特别是,我们表明,对于接近体相玻璃转变温度的温度,测量类似液体的可移动层时,在确定玻璃转变温度附近增强表面流动性的温度相关长度尺度方面,可能具有非常有限的预测能力。这对测量这种增强的表面动力学对玻璃状材料中动力学相关性长度尺度的讨论的能力提出了重要的限制。