Finneran Ian A, Holland Daniel B, Carroll P Brandon, Blake Geoffrey A
Department of Chemistry, California Institute of Technology, Pasadena, California 91125, USA.
Rev Sci Instrum. 2013 Aug;84(8):083104. doi: 10.1063/1.4818137.
Chirped pulse Fourier transform microwave (CP-FTMW) spectrometers have become the instrument of choice for acquiring rotational spectra, due to their high sensitivity, fast acquisition rate, and large bandwidth. Here we present the design and capabilities of a recently constructed CP-FTMW spectrometer using direct digital synthesis (DDS) as a new method for chirped pulse generation, through both a suite of extensive microwave characterizations and deep averaging of the 10-14 GHz spectrum of jet-cooled acetone. The use of DDS is more suited for in situ applications of CP-FTMW spectroscopy, as it reduces the size, weight, and power consumption of the chirp generation segment of the spectrometer all by more than an order of magnitude, while matching the performance of traditional designs. The performance of the instrument was further improved by the use of a high speed digitizer with dedicated signal averaging electronics, which facilitates a data acquisition rate of 2.1 kHz.
啁啾脉冲傅里叶变换微波(CP-FTMW)光谱仪因其高灵敏度、快速采集速率和大带宽,已成为获取旋转光谱的首选仪器。在此,我们通过一系列广泛的微波特性表征以及对喷射冷却丙酮10 - 14 GHz光谱的深度平均,展示了一种最近构建的使用直接数字合成(DDS)作为啁啾脉冲生成新方法的CP-FTMW光谱仪的设计和性能。DDS的使用更适合CP-FTMW光谱的原位应用,因为它将光谱仪啁啾生成部分的尺寸、重量和功耗均降低了一个多数量级以上,同时性能与传统设计相当。通过使用带有专用信号平均电子设备的高速数字化仪,进一步提高了该仪器的性能,其数据采集速率可达2.1 kHz。