手性自组装和通过主客体识别的多金属氧酸盐配合物的可逆光调控。
Chiral self-assembly and reversible light modulation of a polyoxometalate complex via host-guest recognition.
机构信息
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China.
出版信息
Chem Commun (Camb). 2013 Oct 28;49(84):9770-2. doi: 10.1039/c3cc45848b.
PMID:24022786
Abstract
Chiral self-assembly of an azobenzene-grafted POM complex has been constructed through self-crosslinking by both the electrostatic and host-guest interactions and reversibly modulated by dynamic controlling of the isomerization of photoactive groups in the complex.
摘要
通过静电相互作用和主客体相互作用的自交联，构建了一个偶氮苯接枝的多酸配合物的手性自组装体，并通过光活性基团在配合物中的异构化的动态控制，对其进行了可逆调节。
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