Wei Guo-Feng, Sun Sheng, Wang Cheng-Xing, Zhang Bing-Jian, Chen Xi-Min
Department of History, Anhui University, Hefei 230039, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Jul;33(7):1973-6.
The traditional lime mortar was investigated by means of scanning electron microscope (SEM), X-ray diffractometry and Fourier transform infrared spectrometry (FTIR). The results show that the mortar from the memorial archway in the southern Anhui province was the organic-inorganic composite materials composed of lime with tung oil or sticky rice. It was found that the excellent performance of the tung oil-lime mortar can be explained by the compact lamellar organic-inorganic composite structure that was produced by carbonization reaction of lime, cross-linking reactions of tung oil and oxygen and complexing reaction of Ca2+ and -COO-. The compact micro-structure of sticky rice-lime mortar, which was produced due to carbonation process of lime controlled by amylopectin, should be the cause of the good performance of this kind of organic-inorganic mortar.
通过扫描电子显微镜(SEM)、X射线衍射仪和傅里叶变换红外光谱仪(FTIR)对传统石灰砂浆进行了研究。结果表明,皖南牌坊的砂浆是由石灰与桐油或糯米组成的有机-无机复合材料。研究发现,桐油-石灰砂浆的优异性能可以通过石灰的碳化反应、桐油与氧气的交联反应以及Ca2+与-COO-的络合反应所产生的致密层状有机-无机复合结构来解释。糯米-石灰砂浆的致密微观结构是由于支链淀粉控制的石灰碳化过程而产生的,这应该是这种有机-无机砂浆性能良好的原因。