水溶性 TPPS 在有机溶剂中的自组装：从纳米纤维到镜像成像手性纳米棒。
Self-assembly of water-soluble TPPS in organic solvents: from nanofibers to mirror imaged chiral nanorods.
机构信息
Beijing National Laboratory for Molecular Science (BNLMS), CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, People's Republic of China.
出版信息
Chem Commun (Camb). 2013 Nov 18;49(89):10498-500. doi: 10.1039/c3cc46467a.
PMID:24084829
Abstract
Water-soluble TPPS was found to self-assemble into long nanofibers of ambiguous chirality in organic solvents, while mirror imaged chiroptical nanorods with controlled chirality were formed when (1R,2R)-(-)- or (1S,2S)-(+)-1,2-diaminocyclohexane was involved during the self-assembly.
摘要
水溶性 TPPS 在有机溶剂中自组装成长而不确定手性的纳米纤维，而当（1R,2R）-（-）-或（1S,2S）-（+）-1,2-二氨基环己烷参与自组装时，则形成具有手性控制的镜像手性纳米棒。
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