一种具有创纪录半波电位的新型中性有机电子给体。
A novel neutral organic electron donor with record half-wave potential.
机构信息
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK.
出版信息
Org Biomol Chem. 2013 Dec 14;11(46):8073-81. doi: 10.1039/c3ob41701h.
PMID:24150102
Abstract
Tricyclic donor 26 has been prepared and is the most reducing neutral ground-state organic molecule known, with an oxidation potential 260 mV more negative than the previous record. Cyclic voltammetry shows that a 2-electron reversible redox process occurs in DMF as solvent at -1.46 V vs. Ag/AgCl.
摘要
三环供体 26 已被制备出来，它是目前已知的最还原的中性基态有机分子，氧化电位比之前的记录低 260 mV。循环伏安法显示，在 DMF 溶剂中，-1.46 V 相对于 Ag/AgCl 时，发生了一个 2 电子可逆的氧化还原过程。
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