Son Jung-Han, Lee Dong Hun, Cho Yong-Jin, Lee Myung-Hyun
School of Electronic and Electrical Engineering, Sungkyunkwan University, Suwon, Gyeonggi-Do, 440-746, Korea.
J Nanosci Nanotechnol. 2013 Nov;13(11):7235-8. doi: 10.1166/jnn.2013.8097.
Prism modules of 20 nm-, 40 nm-, and 60 nm-thick spin-coated silver films both without and with an upper 100 nm-thick spin-coated polymer layer were fabricated for surface plasmon resonance (SPR) image sensor applications. The prism modules were applied to an SPR image sensor system. The coefficients of determination (R2s) for the 20 nm-, 40 nm- and 60 nm-thick silver films without the polymer layer were 0.9231, 0.9901, and 0.9889, respectively, and with the polymer layer 0.9228, 0.9951, and 0.9880, respectively when standard ethanol solutions with 0.1% intervals in the range of 20.0% to 20.5% were applied. The upper polymer layer has no effect on the R2. The prism modules of the 40-nm-thick spin-coated silver films had the highest R2 value of approximately 0.99. The durability of the 40 nm-thick spin-coated silver film with the 100 nm-thick polymer layer is much better than that without the upper low-loss polymer layer. The developed SPR image sensor module of the 40 nm-thick spin-coated silver film with the upper 100 nm-thick low-loss polymer film is expected to be a very cost-effective and robust solution because the films are formed at low temperatures in a short period of time without requiring a vacuum system and are very durable.
制备了厚度分别为20纳米、40纳米和60纳米的旋涂银膜棱镜模块,这些银膜既有未覆盖上层100纳米厚旋涂聚合物层的,也有覆盖了上层100纳米厚旋涂聚合物层的,用于表面等离子体共振(SPR)图像传感器应用。这些棱镜模块被应用于一个SPR图像传感器系统。对于未覆盖聚合物层的20纳米、40纳米和60纳米厚的银膜,其决定系数(R2)分别为0.9231、0.9901和0.9889;当应用浓度在20.0%至20.5%范围内、间隔为0.1%的标准乙醇溶液时,覆盖聚合物层的相应决定系数分别为0.9228、0.9951和0.9880。上层聚合物层对R2没有影响。40纳米厚旋涂银膜的棱镜模块具有最高的R2值,约为0.99。覆盖100纳米厚聚合物层的40纳米厚旋涂银膜的耐久性比未覆盖上层低损耗聚合物层的要好得多。所开发的带有上层100纳米厚低损耗聚合物膜的40纳米厚旋涂银膜的SPR图像传感器模块预计将是一种非常经济高效且耐用的解决方案,因为这些膜可以在低温下短时间内形成,无需真空系统,并且非常耐用。