（3S,6R）-3-羟基-1,7-二氧杂螺[5.5]十一烷及其（4R）-4-羟基异构体[橄榄果实蝇（Dacus oleae）性信息素的次要成分]的对映选择性合成。
Enantiospecific synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane and its (4R)-4-hydroxy isomer [minor components of olive fruit fly (Dacus oleae) sex pheromone].
机构信息
Department of Organic Chemistry Faculty of Pharmacy, University of Granada, 18071, Granada, Spain.
出版信息
J Chem Ecol. 1992 Feb;18(2):115-25. doi: 10.1007/BF00993747.
PMID:24254903
Abstract
The synthesis of (3S,6R)-3-hydroxy-1,7-dioxaspiro[5.5]undecane (8) and its (4R)-4-hydroxy isomer (11) from (3R,4S,6R)-3,4-dihydroxy-1,7-dioxaspiro[5.5]undecane (1), obtained from D-fructose, has been accomplished by regioselective deoxygenation at C-4 and C-3, respectively, of the appropriately protected derivatives.
摘要
（3S,6R）-3-羟基-1,7-二氧杂螺[5.5]十一烷（8）及其（4R）-4-羟基异构体（11）可分别由（3R,4S,6R）-3,4-二羟基-1,7-二氧杂螺[5.5]十一烷（1）（来源于 D-果糖）经区域选择性脱氧得到，其中相应保护的衍生物的 C-4 和 C-3 位分别进行了脱氧反应。
Zotero 插件