Department of Entomology, University of California, 92521, Riverside, California.
J Chem Ecol. 1990 Dec;16(12):3393-409. doi: 10.1007/BF00982106.
Two sex pheromone components, 3(Z),6(Z),9(Z)-nonadecatriene (3Z,6Z,9Z-19 ∶ H), and 3(Z),6(Z),9(Z)-eicosatriene (3Z,6Z,9Z-20∶ H), have been positively identified, and a third component, 6(Z),9(Z)-nonadecadiene (6(Z),9(Z)-19 ∶ H) has been tentatively identified from abdominal tip extracts of female spring cankerworm moths,Paleacrita vernata Peck (Lepidoptera∶ Geometridae). The pheromone components were identified by a combination of gas chromatography, electroantennography, mass spectrometry, chemical tests, comparison with standards, and field testing. Only 3Z,6Z,9Z-20 ∶ H exhibited significant attractant activity when tested alone, and it was potentiated by the other two components. The attractive blend was an 8∶2∶1 ratio of 3Z,6Z,9Z-20∶H/3Z,6Z,9Z-19∶H/6Z,9Z-19∶H. However, the two-component blend of 3Z,6Z,9Z-20 ∶ H and 6Z,9Z-19 ∶ H (8∶1 ratio) was as attractive as the three-component blend in further field tests. A series of related compounds, the diene monoepoxides available from epoxidation of C19 and C20 3Z,6Z,9Z-trienes, some of which have been found in the pheromone blends of other moth species, were tested as behavioral antagonists. The attraction of male moths to synthetic lures was suppressed by the addition of 6Z,9Z-cis-3,4-epoxy-nonadecadiene to the lures. Additional experiments were performed to determine the effects of lure dosage, trap height, and trap design on the numbers of male moths captured.
已从雌性春尺蠖蛾,Paleacrita vernata Peck(鳞翅目:尺蛾科)腹部末端提取物中鉴定出两种性信息素成分,3(Z),6(Z),9(Z)-十九碳三烯(3Z,6Z,9Z-19 ∶ H)和 3(Z),6(Z),9(Z)-二十碳三烯(3Z,6Z,9Z-20∶ H),并且已从腹部末端提取物中鉴定出第三种成分,6(Z),9(Z)-十九碳二烯(6(Z),9(Z)-19 ∶ H)。这些性信息素成分是通过气相色谱、触角电位、质谱、化学测试、与标准品比较和田间测试相结合来鉴定的。单独测试时,只有 3Z,6Z,9Z-20∶ H 表现出显著的引诱活性,并且其他两种成分可增强其活性。具有吸引力的混合物是 3Z,6Z,9Z-20∶ H/3Z,6Z,9Z-19∶ H/6Z,9Z-19∶ H 的 8∶2∶1 比例。然而,在进一步的田间试验中,3Z,6Z,9Z-20∶ H 和 6Z,9Z-19∶ H(8∶1 比例)的两种成分混合物与三种成分混合物一样具有吸引力。一系列相关化合物,即 C19 和 C20 3Z,6Z,9Z-三烯的环氧化产物,单二烯环氧化物,已在其他蛾种的性信息素混合物中发现,已被测试为行为拮抗剂。雄性飞蛾对合成诱饵的吸引力因向诱饵中添加 6Z,9Z-顺式-3,4-环氧-十九碳二烯而受到抑制。还进行了额外的实验,以确定诱饵剂量、诱捕器高度和诱捕器设计对捕获雄性飞蛾数量的影响。