澳大利亚革蚁属头部的新型吡嗪。

Novel pyrazines from the head of Australian ponerine antRhytidoponera metallica.

机构信息

Department of Organic Chemistry, University of New South Wales, P.O. Box 1, 2033, Kensington, New South Wales, Australia.

出版信息

J Chem Ecol. 1987 Aug;13(8):1811-22. doi: 10.1007/BF01013230.

DOI:10.1007/BF01013230

PMID:24302390

Abstract

The novel pyrazines, (E)- and (Z)-5-methyl-3-(2-methylbutyl)-2-(3-methylbut-1-enyl)pyrazine, (E)- and (Z)-5-methyl-3-isopentyl-2-(3-methylbut-1-enyl) pyrazine, (E)- and (Z)-5-methyl-3-(2-methylbutyl)-2-(3-methylpent-1-enyl)pyrazine, (E)- and (Z)-5-methyl-3-isopentyl-2-(3-methylpentl-enyl) pyrazine, together with the known pyrazines, 2,5-dimethyl-3-(2-methylbutyl)pyrazine and 2,5-dimethyl-3-isopentylpyrazine, have been identified from the head of the Australian ponerine antRhytidoponera metallica. Alkanes and alkenes, in small amounts, were also detected.

摘要

新型吡嗪类化合物 (E)-和 (Z)-5-甲基-3-(2-甲基丁基)-2-(3-甲基丁-1-烯基)吡嗪、(E)-和 (Z)-5-甲基-3-异戊基-2-(3-甲基丁-1-烯基)吡嗪、(E)-和 (Z)-5-甲基-3-(2-甲基丁基)-2-(3-甲基戊-1-烯基)吡嗪、(E)-和 (Z)-5-甲基-3-异戊基-2-(3-甲基戊-1-烯基)吡嗪，以及已知的吡嗪类化合物 2,5-二甲基-3-(2-甲基丁基)吡嗪和 2,5-二甲基-3-异戊基吡嗪，已经从澳大利亚蚁科切叶蚁 Rhytidoponera metallica 的头部中鉴定出来。还检测到少量的烷烃和烯烃。