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一项可视化并确定交叉墨线顺序的研究。

A study to visualize and determine the sequencing of intersecting ink lines.

作者信息

Ozbek Nil, Braz André, López-López Maria, García-Ruiz Carmen

机构信息

Department of Chemistry, Faculty of Arts & Science, Istanbul Technical University, Maslak, Istanbul 34469, Turkey.

University Institute of Research in Police Sciences, University of Alcalá, Ctra. Madrid-Barcelona Km. 33.600, Alcalá de Henares, 28871 Madrid, Spain; Department of Analytical Chemistry, Physical Chemistry and Chemical Engineering, Multipurpose Building of Chemistry, University of Alcalá, Ctra. Madrid-Barcelona Km. 33.600, Alcalá de Henares, 28871 Madrid, Spain.

出版信息

Forensic Sci Int. 2014 Jan;234:39-44. doi: 10.1016/j.forsciint.2013.10.026. Epub 2013 Oct 31.

Abstract

Determining the sequencing of intersecting ink lines is one of the current problems for forensic document examiners. The way two inks will distribute and interact with each other and the paper at the crossing is a dynamic process that can be affected by many variables. Thus, the main purpose of this manuscript is to visualize and have a more comprehensive understanding of this process as well as study a methodology for determining the correct order of intersecting ink lines. For this, overlapping layers of different types of inks from writing instruments and printers were cross-sectioned and examined with a microscope. Results from pen/pen crossings showed that liquid-liquid and gel-gel intersections tended to form a double layer but oil-oil intersections usually formed mixtures. Additionally, oil-liquid and oil-gel intersections tended to form a double layer whenever the oil ink was on top and liquid-gel intersections tended to form a double layer for almost all crossings with exception of the ones involving a gel pen ink from one manufacturer. Results from pen/printer crossings showed the formation of a double layer only when the printer ink was on top of the pen ink. On the other permutation, the pen ink tended to penetrate through the printer ink producing the mixture of both inks. The inks drying time was found to be an important factor affecting the interaction between two inks in a crossing, particularly crossings involving gel pen inks. On the contrary, the type of paper and the writing pressure showed no significant influence on the inks distribution at the crossing. The methodology developed was reproducible with overlapping layers but there were many experimental difficulties during the validation process of intersections representing real crossings. Moreover, interpretation was dependent on the operator's eye which was a limiting factor.

摘要

确定交叉墨水线条的先后顺序是法医文件检验人员目前面临的问题之一。两种墨水在交叉处相互之间以及与纸张的分布和相互作用方式是一个动态过程,会受到许多变量的影响。因此,本手稿的主要目的是可视化并更全面地了解这一过程,同时研究一种确定交叉墨水线条正确顺序的方法。为此,对书写工具和打印机的不同类型墨水的重叠层进行了横截面处理,并使用显微镜进行检查。钢笔与钢笔交叉的结果表明,液 - 液和凝胶 - 凝胶交叉处往往会形成双层,但油 - 油交叉处通常会形成混合物。此外,当油性墨水在上层时,油 - 液和油 - 凝胶交叉处往往会形成双层,而液 - 凝胶交叉处几乎在所有交叉情况下都会形成双层,但涉及某一制造商凝胶笔墨水的交叉情况除外。钢笔与打印机交叉的结果表明,只有当打印机墨水位于钢笔墨水之上时才会形成双层。在其他排列情况下,钢笔墨水往往会穿透打印机墨水,产生两种墨水的混合物。发现墨水干燥时间是影响交叉处两种墨水相互作用的一个重要因素,特别是涉及凝胶笔墨水的交叉情况。相反,纸张类型和书写压力对交叉处墨水的分布没有显著影响。所开发的方法对于重叠层是可重复的,但在代表实际交叉情况的交叉处验证过程中存在许多实验困难。此外,解释依赖于操作人员的肉眼,这是一个限制因素。

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