地球堿金属硅烷基的氢硅烷化催化作用：双(三苯基硅基)钙的合成、表征和反应性。
Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium.
机构信息
Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany.
出版信息
Chem Commun (Camb). 2014 Mar 4;50(18):2311-4. doi: 10.1039/c3cc49308c. Epub 2014 Jan 21.
PMID:24445933
Abstract
Bis(triphenylsilyl)calcium [Ca(SiPh3)2(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.
摘要
高收率得到的结晶醚加合物双(三苯基硅基)钙[Ca(SiPh3)2(thf)]高效且区域选择性地催化活化的 C-C 双键的硅氢化反应。
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