The Hong Kong Polytechnic University Shenzhen Research Institute, Shenzhen, PR China.
Lab Chip. 2014 Mar 21;14(6):1074-82. doi: 10.1039/c3lc51233a.
Photocatalytic water purification utilizes light to degrade the contaminants in water and may enjoy many merits of microfluidics technology such as fine flow control, large surface-area-to-volume ratio and self-refreshing of reaction surface. Although a number of microfluidic reactors have been reported for photocatalysis, there is still a lack of a comprehensive review. This article aims to identify the physical mechanisms that underpin the synergy of microfluidics and photocatalysis, and, based on which, to review the reported microfluidic photocatalytic reactors. These microreactors help overcome different problems in bulk reactors such as photon transfer limitation, mass transfer limitation, oxygen deficiency, and lack of reaction pathway control. They may be scaled up for large-throughput industrial applications of water processing and may also find niche applications in rapid screening and standardized tests of photocatalysts.
光催化水净化利用光来降解水中的污染物,并可能享有微流控技术的许多优点,如精细的流量控制、大的表面积与体积比以及反应表面的自我更新。尽管已经有许多用于光催化的微流控反应器被报道,但仍缺乏全面的综述。本文旨在确定微流控和光催化协同作用的物理机制,并在此基础上综述报道的微流控光催化反应器。这些微反应器有助于克服体相反应器中的不同问题,如光子传递限制、传质限制、缺氧和缺乏反应途径控制。它们可以扩展到用于水净化的高通量工业应用,并且还可能在快速筛选和标准化测试催化剂方面找到应用。