铁(III)-氧代金属有机骨架中电子-空穴对的延迟复合。
Delayed electron-hole pair recombination in iron(III)-oxo metal-organic frameworks.
机构信息
Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001, Heverlee, Belgium.
出版信息
Phys Chem Chem Phys. 2014 Mar 21;16(11):5044-7. doi: 10.1039/c3cp55028a.
PMID:24481514
Abstract
The photodynamic properties of a series of Fe(III)-MOFs have been examined via redox reactions with N,N,N',N'-tetramethyl-p-phenylenediamine as an electron donor and methyl viologen as an electron acceptor. Furthermore, photogeneration of long-lived species in MIL-88B(Fe) has been proven via transient absorption spectroscopy.
摘要
通过以 N,N,N',N'-四甲基对苯二胺作为电子给体和甲紫精作为电子受体的氧化还原反应，研究了一系列 Fe(III)-MOFs 的光动力性质。此外，通过瞬态吸收光谱证明了 MIL-88B(Fe)中长寿命物种的光生成。
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