Faculty of Industrial Chemistry and Environmental Engineering, 'Politehnica' University of Timisoara, 6 Pîrvan Blv., RO-300223, Timisoara, Romania E-mail:
Water Sci Technol. 2014;69(6):1234-40. doi: 10.2166/wst.2013.827.
A magnetic iron oxide nanopowder (MnP), prepared by a simple and efficient combustion synthesis technique, was tested for the removal of the anionic dye Congo Red (CR) from aqueous solution. The influence of solution pH, adsorbent dose, temperature, contact time and initial dye concentration on the adsorption of CR onto MnP were investigated. It was shown that the CR adsorption was pH dependent and the adsorption mechanism was governed by electrostatic forces. The adsorption kinetic was best described by the pseudo-second-order model and the equilibrium data were well fitted to the Langmuir isotherm, yielding maximum adsorption capacity of 54.46 mg g(-1). The undeniable advantages of the MnP adsorbent such as inexpensive preparation method, good adsorption capacity and easy separation using an external magnetic field, recommend it as a promising candidate for the removal of anionic dyes from polluted water.
一种磁性氧化铁纳米粉末(MnP),通过简单有效的燃烧合成技术制备而成,被用于从水溶液中去除阴离子染料刚果红(CR)。考察了溶液 pH 值、吸附剂用量、温度、接触时间和初始染料浓度对 MnP 吸附 CR 的影响。结果表明,CR 的吸附与 pH 值有关,吸附机制受静电力控制。吸附动力学最符合准二级模型,平衡数据很好地符合朗缪尔等温线,最大吸附容量为 54.46mg g(-1)。MnP 吸附剂具有制备方法廉价、吸附容量高、易于在外磁场中分离等不可否认的优点,推荐其作为去除污染水中阴离子染料的一种有前途的候选材料。