Kim Sung-Jo, Kim Jong-Hyun
Department of Physics, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon 305-764, Korea.
Soft Matter. 2014 Apr 21;10(15):2664-70. doi: 10.1039/c3sm53092b.
We have investigated interactions of colloidal particles with weak homeotropic anchoring energy in homogeneous nematic liquid crystal cells. Particle-wall and inter-particle interactions were observed experimentally and analyzed using typical dipole-dipole and quadrupole-quadrupole interactions, including substrate effects as the image charges. Both experimental results matched well with the calculated results for the effective particle radius reflecting the weak anchoring. The effective radius is reduced by the amount of extrapolation length than the actual particle radius. The effective radii of polyethylene micro-particles were reduced to a coefficient ζ (0.78 ≥ ζ ≥ 0.52) times the actual radius with anchoring coefficients in the range of 3.8 × 10(-6) to 1.4 × 10(-6) J m(-2). The anchoring energy of the particles is, therefore, a key component for explaining liquid crystal colloidal systems.
我们研究了具有弱垂直锚定能的胶体粒子在均匀向列相液晶盒中的相互作用。通过典型的偶极 - 偶极和四极 - 四极相互作用对粒子 - 壁和粒子间相互作用进行了实验观察和分析,其中包括作为镜像电荷的衬底效应。两个实验结果与反映弱锚定的有效粒子半径的计算结果都匹配良好。有效半径比实际粒子半径减小了外推长度的量。聚乙烯微粒的有效半径减小到实际半径的系数ζ(0.78≥ζ≥0.52)倍,锚定系数范围为3.8×10^(-6)至1.4×10^(-6) J m^(-2)。因此,粒子的锚定能是解释液晶胶体系统的关键因素。