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近年来用于检测氰根离子的荧光和比色化学传感器的发展进展。

Recent progress in the development of fluorometric and colorimetric chemosensors for detection of cyanide ions.

机构信息

Department of Chemistry and Nano Science, Global Top 5 Research Program, Ewha Womans University, Seoul 120-750, Korea.

出版信息

Chem Soc Rev. 2014 Jul 7;43(13):4312-24. doi: 10.1039/c4cs00008k. Epub 2014 Mar 25.

Abstract

The presence of cyanide ions in surface water is not only caused by industrial waste but also by biological processes. Owing to the extreme toxicity of cyanide in physiological systems and its widespread presence in the environment, considerable attention has been given to the development of methods for the detection of cyanide. Among the most simple, inexpensive and rapid methods to detect cyanide ions are chemosensors that rely on fluorometric and colorimetric responses. This review, which focuses on CN(-) fluorescence and colorimetric chemosensors that have been developed since 2010, follows a format in which the sensors are classified according to their structural features and reaction mechanisms. Finally, a general overview of the design of fluorometric and colorimetric chemosensors for CN(-) is provided.

摘要

氰离子在地表水中的存在不仅是由工业废物造成的,也可能是由生物过程引起的。由于氰化物在生理系统中的极端毒性及其在环境中的广泛存在,人们对开发氰化物检测方法给予了相当大的关注。在检测氰化物离子的最简单、最廉价和最快的方法中,有依赖于荧光和比色响应的化学传感器。这篇综述主要关注 2010 年以来开发的 CN(-)荧光和比色化学传感器,其采用了按照结构特征和反应机制对传感器进行分类的格式。最后,提供了用于 CN(-)的荧光和比色化学传感器设计的概述。

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