Zhang Yupeng, Wu Jian, Zhang Ying, Guo Wenbin, Ruan Shenping
J Nanosci Nanotechnol. 2014 Jun;14(6):4303-7. doi: 10.1166/jnn.2014.8038.
Na2Ti3O7 nanotubes was synthesized by a hydrothermal method, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Then the material was coated on Al2O3 ceramic substrate to fabricate humidity sensors using Ag-Pd as interdigitated electrodes. The sensor shows high humidity sensitivity and quick response-recovery time. The impedance changes about five orders of magnitude within humidity range from 11% to 95% relative humidity (RH). At the frequency of 100 Hz, the response time is 2 s and recovery time is 4 s, and the maximum hysteresis is less than 3% RH. Moreover, complex impedance property at different RH was investigated to study sensing mechanism. The results indicate the potential applications of Na2Ti3O7 nanotubes for fabricating high-performance humidity sensors.
采用水热法合成了Na2Ti3O7纳米管,并通过X射线衍射(XRD)、扫描电子显微镜(SEM)和透射电子显微镜(TEM)对其进行了表征。然后将该材料涂覆在Al2O3陶瓷基板上,以Ag-Pd作为叉指电极制备湿度传感器。该传感器具有高湿度敏感性和快速的响应-恢复时间。在相对湿度(RH)为11%至95%的湿度范围内,阻抗变化约五个数量级。在100 Hz频率下,响应时间为2 s,恢复时间为4 s,最大滞后小于3%RH。此外,研究了不同RH下的复阻抗特性以研究传感机制。结果表明Na2Ti3O7纳米管在制备高性能湿度传感器方面具有潜在应用。