Gao Peng, Li An Ran, Tai Ming Hang, Liu Zhao Yang, Sun Darren Delai
School of Civil & Environmental Engineering, Nanyang Technological University (Singapore), 50 Nanyang Avenue, 639798 (Singapore), Fax: (+65) 67900676.
Chem Asian J. 2014 Jun;9(6):1663-70. doi: 10.1002/asia.201400057. Epub 2014 Apr 25.
Photocatalytic degradation of pollutants under visible light provides a new door to solve the water contamination problem by utilizing free and renewable sunlight. The search for highly efficient photocatalysts with hierarchical nanostructures remains crucial for accessing this new door. In this work, a new hierarchical nanostructured photocatalyst is designed and synthesized, for the first time, by anchoring In2S3 flower-like nanostructures on non-woven carbon nanofiber (CNF). The nanostructures of these CNF-In2S3 composites were fine-tuned, with the aim of achieving the highest photocatalytic activity under visible light. The formation mechanism of the hierarchical nanostructure is also investigated. The results indicate that the optimized hierarchical CNF-In2S3 photocatalyst is superior in photodegradation and disinfection efficiency to that of pure In2S3 under visible-light irradiation. The prominent photocatalytic activities of these hierarchical CNF-In2S3 photocatalysts can be attributed to the excellent properties of enhanced light absorption, large surface area, and efficient charge separation, which are all derived from the special three-dimensional hierarchical nanostructures. Therefore, this work presents the great potential of this hierarchical nanostructured CNF-In2S3 photocatalyst in practical environmental remediation fields.
可见光下污染物的光催化降解为利用免费且可再生的阳光解决水污染问题提供了一条新途径。寻找具有分级纳米结构的高效光催化剂对于打开这扇新大门仍然至关重要。在这项工作中,首次通过将In2S3花状纳米结构锚定在非织造碳纳米纤维(CNF)上,设计并合成了一种新型分级纳米结构光催化剂。对这些CNF-In2S3复合材料的纳米结构进行了精细调整,目的是在可见光下实现最高的光催化活性。还研究了分级纳米结构的形成机理。结果表明,优化后的分级CNF-In2S3光催化剂在可见光照射下的光降解和消毒效率优于纯In2S3。这些分级CNF-In2S3光催化剂突出的光催化活性可归因于增强光吸收、大表面积和有效电荷分离的优异性能,这些性能均源自特殊的三维分级纳米结构。因此,这项工作展示了这种分级纳米结构的CNF-In2S3光催化剂在实际环境修复领域的巨大潜力。