二氯-[N-(N,N-二甲基氨基甲脒基)-N',N',4-三甲基苯甲酰肼酰胺]-铂(II)硝基甲烷半溶剂合物
Di-chlorido-[N-(N,N-di-methyl-carbamimido-yl)-N',N',4-tri-methyl-benzohydrazonamide]-platinum(II) nitro-methane hemisolvate.
作者信息
Bolotin Dmitrii S, Bokach Nadezha A, Haukka Matti
机构信息
Department of Chemistry, Saint Petersburg State University, Universitetsky Pr. 26, 198504 Stary Petergof, Russian Federation.
Department of Chemistry, University of Jyväskylä, Finland, PO Box 35, FI-40014University of Jyväskylä, Finland.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 12;70(Pt 4):m131-2. doi: 10.1107/S1600536814003894. eCollection 2014 Apr 1.
In the title compound, [PtCl2(C13H21N5)]·0.5CH3NO2, the Pt(II) atom is coordinated in a slightly distorted square-planar geometry by two Cl atoms and two N atoms of the bidentate ligand. The (1,3,5-tri-aza-penta-diene)Pt(II) metalla ring is slightly bent and does not conjugate with the aromatic ring. In the crystal, N-H⋯Cl hydrogen bonds link the complex mol-ecules, forming chains along [001]. The nitromethane solvent molecule shows half-occupancy and is disordered over two sets of sites about an inversion centre.
在标题化合物[PtCl₂(C₁₃H₂₁N₅)]·0.5CH₃NO₂中，Pt(II)原子由双齿配体的两个Cl原子和两个N原子以稍微扭曲的平面正方形几何构型配位。(1,3,5-三氮杂戊二烯)Pt(II)金属环稍微弯曲，且不与芳环共轭。在晶体中，N—H⋯Cl氢键连接配合物分子，沿[001]形成链。硝基甲烷溶剂分子呈半占据状态，在关于一个反演中心的两组位置上无序排列。
Zotero 插件