Li Bing-Wei, Cai Mei-Chun, Zhang Hong, Panfilov Alexander V, Dierckx Hans
Department of Physics, Hangzhou Normal University, Hangzhou 310036, China.
Zhejiang Institute of Modern Physics and Department of Physics, Zhejiang University, Hangzhou 310027, China.
J Chem Phys. 2014 May 14;140(18):184901. doi: 10.1063/1.4874645.
Chirality is one of the most fundamental properties of many physical, chemical, and biological systems. However, the mechanisms underlying the onset and control of chiral symmetry are largely understudied. We investigate possibility of chirality control in a chemical excitable system (the Belousov-Zhabotinsky reaction) by application of a chiral (rotating) electric field using the Oregonator model. We find that unlike previous findings, we can achieve the chirality control not only in the field rotation direction, but also opposite to it, depending on the field rotation frequency. To unravel the mechanism, we further develop a comprehensive theory of frequency synchronization based on the response function approach. We find that this problem can be described by the Adler equation and show phase-locking phenomena, known as the Arnold tongue. Our theoretical predictions are in good quantitative agreement with the numerical simulations and provide a solid basis for chirality control in excitable media.
手性是许多物理、化学和生物系统最基本的特性之一。然而,手性对称性产生和控制的潜在机制在很大程度上尚未得到充分研究。我们使用俄勒冈振子模型,通过施加手性(旋转)电场来研究化学可激发系统(贝洛索夫 - 扎博廷斯基反应)中手性控制的可能性。我们发现,与之前的研究结果不同,根据场旋转频率,我们不仅可以在场旋转方向上实现手性控制,还可以在相反方向上实现。为了揭示其机制,我们基于响应函数方法进一步发展了一种全面的频率同步理论。我们发现这个问题可以用阿德勒方程来描述,并展示了锁相现象,即所谓的阿诺德舌。我们的理论预测与数值模拟在定量上高度吻合,为可激发介质中的手性控制提供了坚实的基础。