Chuai Xiao-Ming, Yang Liu-Yan, Cheng Shu-Bo, Chen Xiao-Feng, Mu Yun-Song
Huan Jing Ke Xue. 2014 Mar;35(3):951-7.
Lake Taihu and Lake Hulun in southern and northern China were selected for the investigation of differences in the characteristics and influencing factors of phosphorus (P) adsorption on the sediments of these two lakes by laboratory simulation experiment. The results showed that: (1) The P adsorption capacity of sediment in Lake Taihu was much higher than that in Lake Hulun, and the maximum adsorption capability for the sediments in these two lakes was 1428.57 mg x kg(-1) and 56.81 mg x kg(-1), respectively; (2) Compared with the sediments in Lake Hulun, the particle diameters from sediments in Lake Taihu were much smaller, and their specific surface areas were much larger, so their P adsorption capacity were much higher; (3) The equilibrium adsorbed amounts in these two lakes were correlated with the total amounts of Al, Fe, Mn (P < 0.05) and significantly correlated to the contents of active Al, Fe, Si, Mn (P < 0.01). However, there was significant negative correlation between the equilibrium adsorbed amounts and total Si contents for the sediments in these two lakes (P < 0.01); (4) The P adsorption capacity decreased as pH values in the overlying water increased, and the increase of pH values affected the adsorption behavior of phosphorus on the sediments in Lake Taihu much more obviously. Therefore, the characteristics of sediments and the variations of pH values in the overlying water affected the adsorption behavior of P on sediments in lake water body.
选取中国南方的太湖和北方的呼伦湖,通过实验室模拟实验研究这两个湖泊沉积物磷(P)吸附特征及影响因素的差异。结果表明:(1)太湖沉积物的磷吸附容量远高于呼伦湖,这两个湖泊沉积物的最大吸附量分别为1428.57 mg·kg⁻¹和56.81 mg·kg⁻¹;(2)与呼伦湖沉积物相比,太湖沉积物的粒径更小,比表面积更大,因此其磷吸附容量更高;(3)这两个湖泊的平衡吸附量与Al、Fe、Mn总量相关(P < 0.05),与活性Al、Fe、Si、Mn含量显著相关(P < 0.01)。然而,这两个湖泊沉积物的平衡吸附量与总Si含量之间存在显著负相关(P < 0.01);(4)上覆水pH值升高时,磷吸附容量降低,且pH值升高对太湖沉积物中磷的吸附行为影响更明显。因此,沉积物特征及上覆水pH值变化影响了湖泊水体中沉积物对磷的吸附行为。