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发光金属有机框架作为爆炸物传感器

Luminescent metal-organic frameworks as explosive sensors.

作者信息

Banerjee Debasis, Hu Zhichao, Li Jing

机构信息

Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA.

出版信息

Dalton Trans. 2014 Jul 28;43(28):10668-85. doi: 10.1039/c4dt01196a.

Abstract

Metal organic frameworks (MOFs) are of enormous current interest not only because of their fundamental importance but also due to their great potential for possible applications in gas storage and separation, catalysis, imaging and sensing, to name a few. Recent studies on luminescent MOFs (LMOFs) in both bulk and nanoparticle forms have shown that these materials possess excellent luminescence emission properties that may be utilized to effectively detect high explosive substances. Developing highly sensitive, selective, fast-responding and fully reversible sensors for explosives' detection is in great demand for the homeland security, environmental safety and other humanitarian concerns. In this perspective article, we discuss the development, possible mechanism and future aspects of explosive sensing by LMOF materials.

摘要

金属有机框架材料(MOFs)目前备受关注,这不仅是因为它们具有重要的基础意义,还由于它们在气体储存与分离、催化、成像与传感等诸多领域具有巨大的潜在应用价值。近期对块状和纳米颗粒形式的发光金属有机框架材料(LMOFs)的研究表明,这些材料具有优异的发光发射特性,可用于有效检测高爆炸物。为满足国土安全、环境安全及其他人道主义需求,开发用于爆炸物检测的高灵敏度、高选择性、快速响应且完全可逆的传感器具有迫切需求。在这篇观点文章中,我们讨论了LMOF材料用于爆炸物传感的发展、可能机制及未来展望。

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