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Enhancement of optical Faraday effect of nonanuclear Tb(III) complexes.

作者信息

Nakanishi Takayuki, Suzuki Yuki, Doi Yoshihiro, Seki Tomohiro, Koizumi Hitoshi, Fushimi Koji, Fujita Koji, Hinatsu Yukio, Ito Hajime, Tanaka Katsuhisa, Hasegawa Yasuchika

机构信息

Faculty of Engineering and ‡Faculty of Science, Hokkaido University , N13 W8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan.

出版信息

Inorg Chem. 2014 Jul 21;53(14):7635-41. doi: 10.1021/ic5009363. Epub 2014 Jun 23.

DOI:10.1021/ic5009363
PMID:24956446
Abstract

The effective magneto-optical properties of novel nonanuclear Tb(III) complexes with Tb-O lattice (specifically, Tb9(sal-R)16(μ-OH)10NO3(-), where sal-R = alkyl salicylate (R = -CH3 (Me), -C2H5 (Et), -C3H7 (Pr), or -C4H9 (Bu)) are reported. The geometrical structures of these nonanuclear Tb(III) complexes were characterized using X-ray single-crystal analysis and shape-measure calculation. Optical Faraday rotation was observed in nonanuclear Tb(III) complexes in the visible region. The Verdet constant per Tb(III) ion of the Tb9(sal-Me) complex is 150 times larger than that of general Tb(III) oxide glass. To understand their large Faraday rotation, electron paramagnetic resonance measurements of Gd(III) complexes were carried out. In this Report, the magneto-optical relation to the coordination geometry of Tb ions is discussed.

摘要

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